ORNL Team 3D Prints Device for Improving Carbon Capture Technology

According to the United Nations Intergovernmental Panel on Climate Change (IPCC), we have less than ten years to cut greenhouse gas (GHG) emissions by 45 percent to prevent runaway climate change. Some environmentalists argue that even that projection is too optimistic. To prevent the collapse of our ecosystem, some researchers are betting on a technology called carbon capture and storage (CCS). This includes a team at the U.S. Department of Energy’s Oak Ridge National Laboratory (ORNL), which has 3D printed an aluminum device for improving carbon capture at fossil fuel plants and other industrial sites.

While carbon capture can be performed in several different ways, the most common method involves attempting to filter carbon dioxide (CO2) from a smokestack using a solvent, such as monoethanolamine, that separates the GHG from the flue gasses. As the CO2 meets the solvent, heat that is produced can reduce the ability of the solvent to react with the CO2, limiting its efficiency.

Image courtesy of RMCMI.

ORNL improved the efficiency of this process by creating a device that integrates with a heat exchanger with a mass-exchanging contactor to remove excess heat. The item was tested within a circular device measuring one meter high by eight inches wide and made up of seven stainless-steel packing pieces. Installed in the top half of the column between packing elements, the 3D-printed part allowed for the integration of a heat exchanger. In turn, the group was able to reduce temperatures and, therefore, improve CO2 capture.

In 2019, ORNL researchers Costas Tsouris and Eduardo Miramontes operated the intensified device inside of the absorption column, which contains commercial stainless-steel packing elements. Credit: Carlos Jones/ORNL, U.S. Dept. of Energy

The project’s Principal Investigator, Xin Sun, explained how such a process was previously unattainable: “Prior to the design of our 3D printed device, it was difficult to implement a heat exchanger concept into the CO2 absorption column because of the complex geometry of the column’s packing elements. With 3D printing, the mass exchanger and heat exchanger can co-exist within a single multifunctional, intensified device.”

Embedded coolant channels within the intensified device reduce the column temperature due to the heat produced during the forward reaction. Credit: Michelle Lehman/ORNL, U.S. Dept. of Energy.

To enable heat exchange within the column, cooling channels were incorporated into the steel packing elements. The 3D-printed component, referred to as the “intensified device” was printed from aluminum due to its high thermal conductivity, overall structural strength and its printability.

Costas Tsouris, one of ORNL’s lead researchers on the project, said of the item’s name, “We call the device intensified because it enables enhances mass transfer through in-situ cooling. Controlling the temperature of adsorption is critical to capturing CO2.”

ORNL’s Costas Tsouris, Xin Sun and Eduardo Miramontes, pictured in early March, demonstrated that the 3D-printed intensified device substantially enhanced carbon dioxide capture efficiency. Credit: Carlos Jones/ORNL, U.S. Dept. of Energy.

Lonnie Love, Lead Manufacturing Researcher at ORNL, said that the intensified device was not limited to aluminum:

“The device can also be manufactured using other materials, such as emerging high thermal conductivity polymers and metals. Additive manufacturing methods like 3D printing are often cost-effective over time because it takes less effort and energy to print a part versus traditional manufacturing methods.”

According to some estimates, carbon capture used to reduce emissions from fossil fuel plants could cut CO2 by 55 to 90 percent. However, the bigger issue is not just removing GHGs from the source, but what is done with the material once it’s removed. In the short term, CO2 is already used to extract oil from wells, with the material injected into wells to drive out crude oil. In other words, carbon capture is actively contributing to climate change and the resulting ecological collapse because it is increasing the use of fossil fuels obtained through this enhanced oil recovery.

Long-term storage is another issue. Hypothetically, after CO2 is transported via pipeline as a liquid or gas, it could then be stored underground or underwater in geological formations. Though it may be technically feasible, it has not been tested extensively and we do not know what the side effects of storing excess CO2 underground or underwater.  Similar to the short-term problem, this solution disincentivizes fossil fuel dependent civilization from shifting to alternative energy sources because it suggests that fossil fuel use can continue indefinitely if we capture it at the source and store it under the earth with unforeseeable consequences using yet-to-be-developed technologies.

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nTopology is ORNL’s new partner to industrialize AM technology

New York-based software company, nTopology has entered into a Cooperative Research and Development Agreement (CRADA) with Oak Ridge National Laboratory (ORNL). The parties aim to develop advanced additive manufacturing capabilities, commercially available to the broader market. Integrating nTopology’s software into ORNL’s machine control capabilities, the collaboration aims to optimize the manufacturing process, including build speed […]

GE, ORNL, PARC receive $1.3 million to accelerate energy products with additive manufacturing

GE, Oak Ridge National Laboratory (ORNL), Tennessee, and the Palo Alto Research Center (PARC), a Xerox company, have been awarded an estimated $1.3 million to accelerate the development of 3D printed turbomachinery parts. “Totally Impactful” The funds were granted by the U.S. Advanced Research Projects Agency-Energy (ARPA-E) Design Intelligence Fostering Formidable Energy Reduction and Enabling Novel Totally Impactful Advanced Technology Enhancements (DIFFERENTIATE) program. Within the DIFFERENTIATE program, the partners […]

State of the Art: Carbon Fiber 3D Printing, Part Six

One topic we’ve skirted around in our carbon fiber series so far is large-scale composite printing processes. The reason for this is because it is both a big topic, literally and figuratively and involves material mixes that don’t quite fit with the continuous carbon fiber reinforcements we’ve discussed so far.

The BAAM 3D printer. Image courtesy of ORNL.

Oak Ridge National Laboratory (ORNL) is a pioneer in this space because the U.S. Department of Energy Lab almost single-handedly developed the technology, though it did so with the help of public tax dollars and partnerships with companies in the industry. Working with machine manufacturer Cincinnati Incorporated and Local Motors, ORNL developed the first large-scale plastic pellet 3D printer.

The project team used an old experiment additive construction that consisted of a large gantry system meant for extruding concrete. The printer was retrofitted with a screw extruder to process pellets made up of ABS with roughly five percent chopped carbon fiber filler. Using pellets has the advantage of much faster material handling, as well as reduced cost, since these are the same materials made for injection molding. Since injection molding pellets are available in wide supply and don’t need to be further processed into filament, the price is significantly lower.

The result was the Big Area Additive Manufacturing-CI system. The original BAAM-CI system was capable of printing 40 pounds of material per hour in a build volume of 7 ft x 13 ft x 3 ft. To demonstrate the sheer power of the machine, ORNL and its partners have 3D printed the chassis for a number of vehicles, including cars, boats and excavator cabs.

This Shelby Cobra is 3D-printed. Image courtesy of ORNL.

Since the first BAAM-CI printer was used to create a replica Shelby Cobra, its capabilities have grown greatly. Cincinnati Inc. now offers four sizes ranging from 11.7 ft x 5.4 ft x 3 ft to 20 ft x 7.5 ft x 6 ft, with a feed rate that has doubled to 80 lbs/hr. Cincinnati Inc. now offers a wider portfolio of 3D printers, including a Medium Area Additive Manufacturing system with a 1m x 1m x 1m build volume and 1 kg/hr deposition rate, as well as desktop-sized Small Area Additive Manufacturing printers.

The ability to handle composites with higher carbon fiber content has been achieved, as well. When 3D printing the first vehicle chassis for Local Motors, a 15 percent carbon fiber fill was used. In some cases, up to 50 percent carbon fiber content has been printed. Cincinnati states that “dozens of materials” have been used on its BAAM machines, such as ABS, PPS, PC, PLA, and PEI. In addition to carbon fiber, glass fiber and organic fiber have been used for reinforcement.

Taking a cue from its competitor, CNC manufacturer Thermwood developed its own large-scale additive extrusion technology, the Large Scale Additive Manufacturing (LSAM) series. Available with either a fixed or moving print table, the dual-gantry LSAM series is available with a print volume of 10 ft x 20 ft x 10 ft or 10 ft x 40 ft x 10 ft and can deposit 500 pounds of material per hour. And, while projects made by the BAAM printer require post-processing via CNC milling, the LSAM series has built-in machining capabilities that bring near-net-shape blanks to their final form.

Ingersoll’s MasterPrint was used to 3D print this boat. Image courtesy of Ingersoll.

To beat out everyone else in the manufacturing equipment space, Ingersoll Machine Tools worked with ORNL to develop the MasterPrint 3D printer, capable of 3D printing objects as large as 100 feet long, 20 feet wide and 10 feet tall at rates of 150 lbs/h to 1000 lbs/h. The system also features a CNC tool for machining parts to completion. We should note here that Thermwood claims its LSAM platform can be extended to be 100 feet long, though we have not yet seen such a setup.

Ingersoll sold its first MasterPrint system to the University of Maine, which it used to 3D print a 25-foot, 5,000-pound boat in under 72 hours. The ship, which will be used in a simulation program, had the distinction of achieving a Guinness World Record for the world’s largest solid 3D-printed item and largest 3D-printed boat.

The goal of the printer for Ingersoll is to fabricate massive tools for the aerospace industry. Upon the unveiling of the massive ship, CEO Chip Storie said, “The reality is we went into this technology targeting aerospace and you can print a large aerospace tool in a matter of hours or days where if you go the traditional route, it can take nine or 10 months to be able to build a tool. The cost difference for traditional tooling can run upwards of a million dollars to build an aerospace tool, where you can print a tool using our technology for tens of thousands of dollars. So, there’s a huge cost benefit. There’s a huge time benefit for the aerospace industry.”

The composites being used by these companies may only feature chopped reinforcement materials, but the speed and scale at which they can print is certainly impressive. In the case of Ingersoll, the company is working on incorporating hybrid modules that include fiber placement, tape laying, inspection and trimming.

We may see such systems as these become commonplace in certain manufacturing environments, particularly if continuous reinforcement can be integrated into the process. To learn more about the future of carbon fiber 3D printing, we’ll be looking at research endeavors in this field in our next section in the series.

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AddUp and ORNL enter $2.7 million agreement to advance laser powder bed fusion technology

French industrial 3D printer provider AddUp has entered into a $2.7 million cooperative research and development agreement (CRADA) with the Oak Ridge National Laboratory (ORNL), to develop metal additive manufacturing materials processes for tooling. The partners will focus on advancing laser powder bed fusion (LPBF) technology for novel metal molds used in tooling. Advancing Laser Powder Bed […]

AddUp Partners with ORNL for 3D-Printed Metal Tooling

French metal 3D printing group AddUp has entered into a $2.7 million agreement with the U.S. Department of Energy’s Oak Ridge National Laboratory (ORNL) to push laser powder bed fusion (PBF) for the use of 3D printing metal molds. While additive manufacturing (AM) is regularly used for the production of tooling, the metal mold supply chain has yet to be truly disrupted by the technology. Given its history of making millions of parts within (its part-owner) Michelin’s own tire mold fabrication process, AddUp may be an important actor in this disruption.

The AddUp Group is the result of years of research on the behalf of Michelin to create better, more cost-effective tires. Since 2000, the company began exploring the possibilities of AM for making tire molds, ultimately leading the development of in-house metal 3D printers. Michelin has roughly two dozen such systems installed worldwide 3D printing over a million metal parts annually. The tire-maker then turned to Fives, an industrial engineering firm with over 160 years of experience, to commercialize the technology via a new 50/50 partnership: the AddUp Group.

With ORNL, AddUp hopes to improve the deposition rate of powder bed systems, while maintaining tight management over the metallurgy of the technology and the qualification of steel tooling. For its part, ORNL has long been in the field of advancing 3D printing technology, including the development of Cincinnati Inc’s Big Area Additive Manufacturing system. In the realm of laser PBF, the research lab is at work improving quality control and expanding material sets. ORNL will be able to contribute its expertise in material properties, process parameters with in-situ analysis, and machine learning to deliver validated process parameters and microstructural characterization of AM tool steels.

The research will aim to develop methods to overcome such geometric constraints as overhang angles, thin walls and process repeatability that have prevented metal 3D printing from widespread adoption in the larger world of mass manufacturing and tooling production. The partners will explore the 3D printing of tooling with complex conformal cooling channels for plastic injection molding that cannot be made using traditional methods.

Using HyperWorks, PROTIQ performed topology optimization on an injection mold to remove material where not needed. Conformal cooling was used to shorten cycle times. Images courtesy of Altair.

3D printing injection molding tools could bring about significant benefits. AM marketplace PROTIQ, for instance, uses simulation tools from Altair to perform topology optimization specifically to metal molds, taking into account the loads associated with closing the mold, injecting the material, and closing the mold, as well as the way that heat dissipates throughout the mold.

In one study, PROTIQ removed 75 percent of the weight from a mold, meaning that the tool, which would have normally been too heavy to move by hand, could be changed in the injection molding machine manually. The incorporation of conformal cooling channels into the tool cut cooling time from about 9 or 10 seconds to about 3.2. Altogether, the company suggests that cycle times for injection molding can be reduced by one-third on average.

While PROTIQ, a subsidiary of German industrial manufacturer Phoenix Contact, has developed tools for optimizing and printing injection molding tools, AddUp has its own partnerships to advance its stake in the game. In addition to the new ORNL agreement, the company teamed with French simulation software developers ESI Group to create the Distortion Simulation AddOn module for its 3D printers. AddUp is also working with the IPC trade group to develop a platform for 3D printing injection molds with conformal cooling.

Not only is AddUp shaping up to be a formidable player in the yet-to-be-disrupted space of metal molds, but, with its acquisitions of BeAM and Poly-Shape, it is becoming a significant pillar of the 3D printing industry. Another French 3D printing heavyweight, Prodways, hasn’t been making the news quite as much recently, which makes one wonder if there’s a shake-up taking place in France at the moment.

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GE Additive and ORNL to work together on industrialization of additive manufacturing

Award-winning 3D printer OEM GE Additive has entered into a five-year cooperative research and development agreement (CRADA) with the US Department of Energy’s Oak Ridge National Laboratory (ORNL). Both parties have agreed to focus their research on processes, materials and software in order to drive industrialization and support broader adoption of additive manufacturing technology. “We’re […]

ORNL and UToledo agree to research lightweight advanced materials for automotive

Oak Ridge National Laboratory (ORNL), Tennessee, and the University of Toledo (UToledo) in Ohio have signed a memorandum of understanding (MoU) agreeing to conduct research into the design and manufacturing of advanced materials for the automotive sector. The two institutions will collaborate to gain new knowledge in the field of high-strength, and lightweight automotive materials. […]

ExOne licenses ORNL ceramic-metal 3D printing to make neutron imaging components

Leading binder jet 3D printer provider ExOne has announced that it has licensed a new method of additive manufacturing invented at Oak Ridge National Laboratory (ORNL). Specifically, the method relates to the 3D printing of aluminum-infiltrated boron carbide (B4C), a material used to make components for neutron imaging. A step up from industrial X-rays, neutron imaging is […]

GKN Aerospace commissions Cell 2 additive manufacturing production cell at ORNL

Continuing a $17.8 million agreement with Oak Ridge National Laboratory (ORNL), British multinational manufacturer GKN Aerospace has commissioned a new large scale additive manufacturing production cell. Deemed “Cell 2” the system uses laser metal deposition with wire (LMD-w) technology and will be used to develop large aircraft components for GKN. The commission is an advance on […]